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She is currently one of the highest paid models on the planet and has appeared on the cover of Victoria's Secret and GQ. In 2004, Ambrosio launched her line of swimwear called Alessandra Ambrosio by Sais, a division of Rosa Cha and is continuing to expand into other areas of licensing.

She is best known for her work with Victoria's Secret and was chosen as their first spokes-model for Victoria's Secret Pink line. Aside from modeling work, she is the National Ambassador for the National Multiple Sclerosis Society. Alessandra and Jamie Mazur became the parents of a girl, Anja Louise Ambrosio Mazur, on August 24, 2008 in Brazil. Anja weighed in at 6.3 lb.

Alessandra was ranked # 51 on the Maxim Hot 100 of 07 list. Alessandra and boyfriend are parents of a girl named Anja Louise Ambrosio Mazur, born August 24th 08 in Brazil.